Palladocarbosilane dendrons in supercritical carbon dioxide. Catalytic behaviour in the asymmetric hydrovinylation of styrene

▶ Hydrovinilation of styrene in scCO2 with palladocarbosilane chiral dendrons as catalysts. ▶ Catalytic systems soluble in scCO2. ▶ Good activity and enantiomeric excesses obtained.