کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
66785 | 48450 | 2010 | 8 صفحه PDF | دانلود رایگان |
Novel and environmentally benign Bronsted acidic ionic liquids with SO3-H functionality were prepared using N-methyl imidazole, pyridine, triethylamine and 1,4-butanesultone as the source chemicals. The prepared ionic liquid catalysts were characterized by NMR and their catalytic activity in tert-butylation of p-cresol with tert-butyl alcohol (TBA) was investigated. The effects of reaction time, reaction temperature, reactant mole ratio and the recyclability of the catalysts on the conversion of p-cresol and selectivity to 2-tert-butyl-p-cresol (TBC) and 2,6-di-tert-butyl-p-cresol (DTBC) called butylated hydroxytoluene (BHT) were investigated. Lower alcohol to p-cresol mole ratios, lower ionic liquid to p-cresol ratio and temperature as low as 70 °C gave 80% conversion of p-cresol. The catalyst activity was found to be almost completely retained even after 5 recycles. Extended Arrhenius equation was used to calculate the rate constants for this reaction.
Bronsted acidic ionic liquids with SO3-H functionality were prepared, characterized and their catalytic activity in tert-butylation of p-cresol with tert-butyl alcohol was investigated. Kinetic investigations show lower alcohol to p-cresol mole ratios, lower ionic liquid to p-cresol ratio and temperature as low as 70 °C gave p-cresol conversion. The catalyst activity was retained even after 5 recycles.Figure optionsDownload high-quality image (126 K)Download as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 321, Issues 1–2, 14 April 2010, Pages 34–41