کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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66870 | 48455 | 2010 | 8 صفحه PDF | دانلود رایگان |
Two symmetrical acetylacetone-based Schiff bases were immobilized on a silica surface by grafting and sol–gel procedure. The corresponding supported manganese complexes were prepared and evaluated as heterogeneous catalysts for alkene epoxidation with H2O2. These heterogeneous catalysts show remarkable effectiveness and selectivity towards epoxide formation in the presence of ammonium acetate. Moreover, the developed heterogeneous catalysts preserve the coordination and catalytic properties of the active-homogeneous manganese catalysts for alkene epoxidation vs. the competitive H2O2 dismutation. EPR spectroscopy shows that in heterogeneous manganese catalysts the Mn2+ centers are in a flexible, non-tight, coordination environment, as in the corresponding homogeneous manganese catalysts. However, after a first use of the heterogeneous catalysts, the Mn centers are detached from the ligand and are randomly dispersed on the SiO2 surface. This is responsible for the loss of catalytic activity.
Manganese heterogeneous catalysts with symmetrical acetylacetone-based Schiff bases have been prepared by grafting and sol–gel procedure. They have been evaluated for alkene epoxidation with H2O2 showing remarkable effectiveness and selectivity towards epoxide formation in the presence of ammonium acetate. The developed heterogeneous catalysts preserve the coordination and catalytic properties of the active-homogeneous manganese catalysts for alkene epoxidation vs. the competitive H2O2 dismutation.Figure optionsDownload high-quality image (101 K)Download as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 319, Issues 1–2, 17 March 2010, Pages 58–65