Defect of HY as catalyst for selective catalytic reduction of NO in comparison with the pentasil zeolites

The specific behavior of HY in some steps that possibly occurred in the selective catalytic reduction of NO by hydrocarbon (HC-SCR) was investigated. Experimental results indicated that the activity of HY for NO oxidation to NO2 was much lower than those of the pentasil zeolites (HZSM-5, HFER and HMOR). In addition, FTIR measurements showed that both nitrosonium ions (NO+) and nitrate species were remarkably produced at 300 °C over the pentasil zeolites and they were highly active towards hydrocarbons at the temperature. On the contrary, no NO+ species could be detected over HY and the nitrate species produced over the zeolite were almost inactive towards reduction at the same reaction condition. It is proposed that the low amount of strong Brönsted acids of HY accounts for the above inferior founctions of the zeolite required by HC-SCR, leading to the low NO reduction activity.

Specific behavior of HY in some processes that are possible reaction steps of the selective catalytic reduction of NO by hydrocarbon (HC-SCR) was investigated comparing to those of the pentasil zeolites. It indicated that the following functions of HY weaker than those of the pentasil zeolites should be strengthen for designing practical HC-SCR catalysts based on the zeolite.Figure optionsDownload as PowerPoint slide