کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
672775 | 1459458 | 2016 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Vaporization thermodynamics of Pd-rich intermediate phases in the Pd-Yb system
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The vaporization thermodynamics of several intermediate phases in the Pd-Yb system was investigated by means of vaporization experiments performed under Knudsen conditions (KEML, Knudsen Effusion Mass Loss). The following thermal decomposition processes were studied in the overall temperature range 819-1240 K and their enthalpy changes determined: 4 PdYb(s) = Pd4Yb3(s) + Yb(g); 5/3 Pd4Yb3(s) = 4/3 Pd5Yb3(s) + Yb(g); 21/13 Pd5Yb3(s) = 5/13 Pd21Yb10(s) + Yb(g); 1/3 Pd21Yb10(s) = 21/9 Pd3Yb(s) + Yb(g). Additional measurements were performed by KEMS (Knudsen Effusion Mass Spectrometry) on a Pd-rich two-phase sample, which allowed to detect both Yb(g) and Pd(g) in the vapor phase and to determine the atomization enthalpy of the Pd3Yb phase (Pd-rich composition boundary, Pd3.08Yb0.92): Pd3.08Yb0.92(s) = 0.92 Yb(g) + 3.08 Pd(g). The enthalpy of formation of this compound was thereafter determined as â68 ± 2 kJ/mol at. and, by combining this value with the decomposition enthalpies derived by KEML, the enthalpies of formation of the studied Pd-Yb intermediate phases were evaluated (kJ/mol at.): â75 ± 4 (Pd21Yb10), â75 ± 3 (Pd5Yb3), â73 ± 3 (Pd4Yb3), and â66 ± 3 (PdYb). A modified version of the Pd-Yb phase diagram is also reported, re-drawn on the basis of literature data and of new experimental information recently become available.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thermochimica Acta - Volume 626, 20 February 2016, Pages 31-36
Journal: Thermochimica Acta - Volume 626, 20 February 2016, Pages 31-36
نویسندگان
A. Ciccioli, G. Balducci, G. Gigli, A. Provino, A. Palenzona, P. Manfrinetti,