کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
673297 1459495 2014 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Dynamic and kinematic viscosities, excess volumes and excess Gibbs energies of activation for viscous flow in the ternary mixture {1- propanol+ N,N-dimethylformamide + chloroform} at temperatures between 293.15 K and 323.15 K
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
Dynamic and kinematic viscosities, excess volumes and excess Gibbs energies of activation for viscous flow in the ternary mixture {1- propanol+ N,N-dimethylformamide + chloroform} at temperatures between 293.15 K and 323.15 K
چکیده انگلیسی


• Many engineering applications require quantitative thermodynamic data of the fluids.
• Excess properties of mixtures are important in the understanding of mixing process.
• The results are used to explain the molecular interaction in the mixtures.

Dynamic and kinematic viscosities, and densities of the ternary mixture {x1 propanol + x2 DMF + x3 chloroform} and of the three corresponding binary systems have been measured at 293.15, 303.15, 313.15 and 323.15 K and atmospheric pressure. The thermophysical properties, viscosity deviations (Δη), kinematic viscosity (γ), excess Gibbs energies of activation of viscous flow (G*E) and excess molar volumes (VE) have been calculated from experimental values of dynamic viscosity, η, and density, ρ. The different results have been correlated by the Redlich–Kister equation for the binary mixtures and the Cibulka equation for equation for the ternary ones.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thermochimica Acta - Volume 589, 10 August 2014, Pages 90–99
نویسندگان
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