کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
67465 48484 2007 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Gemini metallomicellar catalysis: Hydrolysis of p-nitrophenyl picolinate catalyzed by Cu(II) and Ni(II) complexes of macrocyclic ligands in gemini surfactant micelles
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Gemini metallomicellar catalysis: Hydrolysis of p-nitrophenyl picolinate catalyzed by Cu(II) and Ni(II) complexes of macrocyclic ligands in gemini surfactant micelles
چکیده انگلیسی

Cu(II) and Ni(II) complexes of two hexaaza macrocyclic ligands with and without pendant hydroxyl groups, 3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane (1) and 3,10-bis(2-ethyl)-1,3,5,8,10,12-hexaazacyclotetradecane (2), were synthesized. Effects of these complexes on the hydrolysis of p-nitrophenyl picolinate (PNPP) in micelles of cationic gemini surfactants with different spacer lengths, alkanediyl-α,ω-bis(dimethyl dodecylammonium bromide) (designated as 12-s-12, s = 2, 3 and 6), have been investigated at 25 °C. The results showed that metallomicelle systems containing gemini surfactants exhibited more efficient activities for hydrolysis of PNPP than those containing the corresponding single-chained conventional surfactant dodecyltrimethyl-ammonium bromide (DTAB). For gemini surfactants, it was found that catalytic activity of the metallomicellar systems containing the surfactant 12-2-12 was lower than those of surfactants 12-3-12 and 12-6-12. In addition, metal complexes of microcyclic ligand 1 bearing pendant hydroxyl groups showed higher catalytic activities than corresponding metal complexes of 2 without hydroxyl group, indicating that ligand hydroxyl groups play an important role for catalyzed hydrolysis of PNPP in metallomicellar systems.

Catalytical hydrolysis of p-nitrophenyl picolinate (PNPP) in metallomicelle systems containing gemini surfactants 12-s-12 and metal complexes of macrocyclic ligands was investigated. Gemini metallomicellar systems were found to exhibit more efficient activities for hydrolysis of PNPP than those containing conventional surfactant dodecyltrimethylammonium bromide (DTAB), and metal complexes of microcyclic ligand 1 bearing pendant hydroxyl groups show higher catalytic activities than corresponding complexes of 2 without hydroxyl group.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 277, Issues 1–2, 16 November 2007, Pages 15–20
نویسندگان
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