کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
67490 | 48484 | 2007 | 5 صفحه PDF | دانلود رایگان |

Hydrogenation properties of p-chloronitrobenzene (CNB) have been studied over Pt/CNTs and PtM/CNTs catalysts (M = Mn, Fe, Co, Ni and Cu) in ethanol at 303 K and normal pressure. The results exhibit that the hydrogenation of p-CNB can be carried out over PtM/CNTs catalysts. Both catalytic activities and yields of p-chloroaniline (CAN) are improved. PtFe/CNTs catalyst exhibits the best catalytic activity (TOF is 0.47 s−1), and PtMn/CNTs catalyst exhibits the highest yield of p-CAN (98.5 mol%). Different reductants have also influence on both catalytic activity and yield of p-CAN. Pt/CNTs(II) catalyst exhibits good catalytic activity and stability on the hydrogenation of p-CNB. PtM/CNTs(II) catalysts exhibit low catalytic activity and high yield of p-CAN.
PtM/CNTs (M = Mn, Fe, Co, Ni and Cu) catalyst can catalyze the hydrogenation of p-chloronitrobenzene in ethanol at 303 K and normal pressure. PtFe/CNTs catalyst exhibits the best catalytic activity (TOF is 0.47 s−1), and PtMn/CNTs catalyst exhibits the highest yield of p-CAN (98.5 mol%). Figure optionsDownload as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 277, Issues 1–2, 16 November 2007, Pages 210–214