کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
67540 | 48486 | 2008 | 5 صفحه PDF | دانلود رایگان |
A simple catalyst LiClO4/Et3N has been developed and demonstrated to efficiently catalyze Michael addition reactions of active methylene compounds to conjugated ketones, nitriles, esters and nitroalkenes with remarkably high yields and in short reaction time. The Michael addition to nitroalkenes and α,β-unsaturated ketones proceeds quantitatively in the usual way, giving the monoaddition product.
A simple catalyst LiClO4/Et3N has been developed and demonstrated to efficiently catalyze Michael addition reactions of active methylene compounds to conjugated ketones, nitriles, esters and nitroalkenes with remarkably high yields and short reaction time. The Michael addition to nitroalkenes and α,β-unsaturated ketones proceeds quantitatively in the usual way, giving the monoaddition products.Figure optionsDownload as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 292, Issues 1–2, 17 September 2008, Pages 44–48