کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
67598 48488 2007 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
16-Membered pentaaza bis(macrocyclic) nickel(II) complexes containing aromatic nitrogen–nitrogen linkers, {[Ni([16]aneN5)]2R}(ClO4)4: Synthesis, characterization and catalytic oxidation of cyclohexene with molecular oxygen
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
16-Membered pentaaza bis(macrocyclic) nickel(II) complexes containing aromatic nitrogen–nitrogen linkers, {[Ni([16]aneN5)]2R}(ClO4)4: Synthesis, characterization and catalytic oxidation of cyclohexene with molecular oxygen
چکیده انگلیسی

New square-planar bis(macrocyclic)dinickel(II) complexes containing phenylene bridges between 16-membered pentaaza macrocyclic subunits have been synthesized via in situ one pot template condensation reaction of aromatic nitrogen–nitrogen linker (R = 1,4-phenylenediamine; benzidine; 4,4′-diaminodiphenylmethan; 4,4′-diaminodiphenylether; 4,4′-diaminodiphenylsulfon), formaldehyde, bis(1,3-diaminopropane) nickel(II) perchlorate and 1,3-dibromopropane in a 1:4:2:2 molar ratio results in the formation of new series of binuclear nickel(II) complexes; 1-phenyl- (1); 1,1′-phenyl- (2); 1,1′-diphenylmethan- (3); 1,1′-diphenylether- (4); 1,1′-diphenylsulfon- (5) bis(1,3,7,11,15-pentaazacyclohexadecane) nickel(II)), {[Ni([16]aneN5)]2R}(ClO4)4′′. The formation of the macrocyclic framework and the mode of bonding of the complexes have been confirmed by data obtained from elemental analyses, FAB, UV–vis, FT-IR, 1H NMR, electronic spectral studies, conductivity and magnetic susceptibility measurements. These complexes have been found to be effective catalysts for the selective oxidation of cyclohexene to 2-cyclohexene-1-one and 2-cyclohexene-2-ol with molecular oxygen as the oxidant.

New square-planar bis(macrocyclic)dinickel(II) complexes containing phenylene bridges between 16-membered pentaaza macrocyclic subunits have been synthesized via in situ one pot template condensation reaction of aromatic nitrogen–nitrogen linker (R = 1,4-phenylenediamine; benzidine; 4,4′-diaminodiphenylmethan; 4,4′-diaminodiphenylether; 4,4′-diaminodiphenylsulfon), formaldehyde, bis(1,3-diaminopropane) nickel(II) perchlorate and 1,3-dibromopropane in a 1:4:2:2 molar ratio results in the formation of new series of binuclear nickel(II) complexes. These complexes have been found to be effective catalysts for the selective oxidation of cyclohexene to 2-cyclohexene-1-one and 2-cyclohexene-2-ol with molecular oxygen as the oxidant. Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 272, Issues 1–2, 2 July 2007, Pages 207–212
نویسندگان
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