کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
67600 48488 2007 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The kinetics of the aluminium bromide catalyzed isomerization of 1-propyl bromide II
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
The kinetics of the aluminium bromide catalyzed isomerization of 1-propyl bromide II
چکیده انگلیسی

The kinetics of the aluminium bromide catalyzed isomerization of 1-propyl bromide corresponds to a nucleophilic displacement of the aliphatic bromine contained in the monomeric and dimeric complexes of the alkyl bromide with aluminium bromide, (1-C3H7BrAlBr3) and (1-C3H7BrAl2Br6), and the antiparallel dipole pair of the dimeric complexes. The initial rate analysis of the isomerization process shows that parallel mixed dipole pairs of the monomeric and dimeric complexes, (1-C3H7Br·AlBr2δ+AlBr4δ−)·(1-C3H7Δ+Br·AlBr3Δ−) and (1-C3H7Δ+Br·AlBr3Δ−)·(1-C3H7Br·AlBr2δ+AlBr4δ−), could also take part in the isomerization process. The kinetics of the process is investigated and the conclusion is that the isomerization does not require the mixed parallel dipole pairs for the reaction.

The kinetics of the aluminium bromide catalyzed isomerization of 1-propyl bromide involves the monomeric and dimeric complexes of the alkyl bromide with aluminium bromide, (1-C3H7BrAlBr3) and (1-C3H7BrAl2Br6), and the antiparallel dipole pair of the dimeric complexes.Figure optionsDownload as PowerPoint slideThe initial rate analysis of the isomerization process now shows that parallel mixed dipole pairs of the monomeric and dimeric complexes, (1-C3H7Br·AlBr2δ+AlBr4δ−)·(1-C3H7Δ+Br·AlBr3Δ−) and (1-C3H7Δ+Br·AlBr3Δ−)·(1-C3H7Br·AlBr2δ+AlBr4δ−), could also take part in the isomerization process. The kinetics of the process is investigated and the conclusion is that the isomerization does not require the mixed parallel dipole pairs for the reaction.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 272, Issues 1–2, 2 July 2007, Pages 220–224
نویسندگان
,