کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
67663 48490 2007 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Sulfonic acid functionalized mesoporous silicas and organosilicas: Synthesis, characterization and catalytic applications
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Sulfonic acid functionalized mesoporous silicas and organosilicas: Synthesis, characterization and catalytic applications
چکیده انگلیسی

Ethane bridged mesoporous organosilicas and MCM-41 having sulfonic acid groups in the pore channels were prepared by co-condensation method as well as grafting method, using 3-mercaptopropyltriethoxysilane (3-MPTS) as the sulfur precursor. TEM and N2 sorption isotherm analysis revealed that the mesoporous structural ordering is retained after the functionalization and modifications of organic groups while FT-IR, Raman, XPS and solid-state 13C CP MAS NMR shows the presence of sulfonic acid groups and the stability of the mesoporous framework. The catalytic activity of the developed materials was evaluated in the liquid phase Claisen–Schmidt condensation reaction of acetophenone with benzaldehyde, to probe the effect of mesoporous support surfaces as well as the role of preparation methods. Results showed that sulfonic acid functionalized ethane–silica samples were more active, selective and stable than the conventional sulfonic acid containing mesoporous catalysts.

Ethane bridged mesoporous organosilicas and MCM-41 having sulfonic acid groups in the pore channels were prepared by co-condensation method as well as grafting method and were used as catalysts in the liquid phase Claisen–Schmidt condensation reaction of acetophenone with benzaldehyde to yield chalcones. Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 274, Issues 1–2, 3 September 2007, Pages 153–158
نویسندگان
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