کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
67680 | 48491 | 2008 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A practical concept for the kinetic resolution of a chiral secondary alcohol based on a polymeric silane
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: A practical concept for the kinetic resolution of a chiral secondary alcohol based on a polymeric silane A practical concept for the kinetic resolution of a chiral secondary alcohol based on a polymeric silane](/preview/png/67680.png)
چکیده انگلیسی
The paper describes our preliminary studies on the use of PMHS as a functionalizable polymer and hydride source for the kinetic resolution of secondary alcohols via chiral Cu(I)-catalyzed dehydrogenative silylating process. The chiral phosphine that chelates the Cu metal center has little influence on the selectivity factor of the kinetic resolution. The use of a stereogenic silane appears to be a key requirement to reach enantiodifferentiation in such a process.
Preliminary studies on the use of PMHS as a functionalizable polymer and hydride source for the kinetic resolution of secondary alcohols via Cu(I)-catalyzed dehydrogenative silylating process is reported and discussed. Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 286, Issues 1–2, 1 May 2008, Pages 6–10
Journal: Journal of Molecular Catalysis A: Chemical - Volume 286, Issues 1–2, 1 May 2008, Pages 6–10
نویسندگان
Jean Thomas Issenhuth, Samuel Dagorne, Stéphane Bellemin-Laponnaz,