کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
68060 48502 2008 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Potassium phthalimide-N-oxyl: An efficient catalyst for cyanosilylation of carbonyl compounds under mild conditions
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Potassium phthalimide-N-oxyl: An efficient catalyst for cyanosilylation of carbonyl compounds under mild conditions
چکیده انگلیسی

Potassium phthalimide-N-oxyl was used as an effective, easy to handle and readily available Lewis basic organocatalyst for the facile addition of trimethylsilyl cyanide to various carbonyl compounds at room temperature under mild conditions to afford corresponding cyanohydrin trimethylsilyl ethers in high to quantitative yields. The high yields of products, high turnover numbers of the catalyst, compatibility of other functional groups, and simplicity in the operation are the advantages of this method.

Potassium phthalimide-N-oxyl was used as an effective, easy to handle and readily available Lewis basic organocatalyst for the facile addition of trimethylsilyl cyanide to various carbonyl compounds under mild conditions. Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 283, Issues 1–2, 18 March 2008, Pages 29–32
نویسندگان
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