کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
68443 | 48514 | 2006 | 4 صفحه PDF | دانلود رایگان |

A variety of hydrocarbons were efficiently oxidized to the corresponding carbonyl compounds in good yields at the ambient temperature with a Schiff base Mn(III) complex as catalyst in the presence of 30% hydrogen peroxide. The oxidation took place selectively at the benzylic C–H bond through a Mn(V)-oxo intermediate. The influence of product yield as a function of solvent, temperature, catalyst concentration and reaction time was evaluated. The reaction is simple, clean and moderately high yield and generates water as the only by-product.
A variety of hydrocarbons were efficiently oxidized to the corresponding carbonyl compounds in good yields at the ambient temperature with a Schiff base Mn(III) complex as catalyst in the presence of 30% hydrogen peroxide. The oxidation took place selectively at the benzylic C–H bond through a Mn(V)-oxo intermediate. Figure optionsDownload as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 259, Issues 1–2, 15 November 2006, Pages 197–200