کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
68512 48516 2008 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Impact of temperature ramping rate during calcination on characteristics of nano-ZrO2 and its catalytic activity for isosynthesis
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Impact of temperature ramping rate during calcination on characteristics of nano-ZrO2 and its catalytic activity for isosynthesis
چکیده انگلیسی

This paper studied the effect of temperature ramping rate during calcination on characteristics of nanoscale zirconia and its catalytic performance for isosynthesis. The physical properties, i.e. BET surface area, cumulative pore volume, cumulative pore diameter and the phase composition in zirconia, acid-base properties and surface properties such as Zr3+ quantity, were characterized. Increase in the temperature ramping rate of calcination resulted in a higher composition of the tetragonal phase, but it showed insignificant influence on the other physical properties. Considering the catalytic activity, the acid sites did not affect the activity, but the basic sites depended on the fraction of the tetragonal phase in zirconia which was related to the selectivity to isobutene. The intensity of Zr3+ on the surface varied with the change in the heating rate of calcination. Both the tetragonal phase composition in zirconia and the quantity of Zr3+ were the key factors affecting the selectivity to isobutene in hydrocarbons. Moreover, the maximum value of the product selectivity to isobutene on the ZrO2 (5.0) catalyst was attained at the highest concentration of Zr3+.

The effect of the temperature ramping rate during calcination on characteristics of nanoscale zirconia and its catalytic performance for isosynthesis was examined.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 280, Issues 1–2, 4 February 2008, Pages 35–42
نویسندگان
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