کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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68515 | 48516 | 2008 | 7 صفحه PDF | دانلود رایگان |

Synthetic talc (magnesium organo silicates; MOS) was synthesized by sol–gel method under non-hydrothermal conditions and modified by introducing amine/diamine functionalities in the interlayer space. The applicability of amine/diamine functionalized MOS was studied as catalysts for the synthesis of jasminaldehyde or α-pentylcinnamaldehyde by condensation of 1-heptanal with benzaldehyde. The effect of amine/diamine functionality, amount of catalyst, benzaldehyde to 1-heptanal molar ratio and temperature on the selectivity of jasminaldehyde was studied in detail. The highest conversion of 1-heptanal (99%) with 82% selectivity of jasminaldehyde was achieved using MOS3 as a catalyst. The rate constant for condensation of 1-heptanal with benzaldehyde was calculated under optimized reaction conditions. This is the first report on application of MOS as a solid base catalyst for the condensation of 1-heptanal with benzaldehyde.
The amine/diamine functionalized synthetic talc (magnesium organo silicates; MOS) was synthesized by sol–gel method under non-hydrothermal conditions and used as a solid base catalyst for synthesis of jasminaldehyde. The highest conversion of 1-heptanal (99%) with 82% selectivity of jasminaldehyde was achieved using MOS3 as a catalyst.Figure optionsDownload as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 280, Issues 1–2, 4 February 2008, Pages 61–67