کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
68721 | 48521 | 2006 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Approach to a better understanding and modelling of β-pyrrolidinoalcohol ligands for enantioselective alkylation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Approach to a better understanding and modelling of β-pyrrolidinoalcohol ligands for enantioselective alkylation Approach to a better understanding and modelling of β-pyrrolidinoalcohol ligands for enantioselective alkylation](/preview/png/68721.png)
چکیده انگلیسی
A series of pyrrolidine-based β-amino alcohols derived from malic acid, citramalic acid and pantolactone with primary amines was prepared and their activity as chiral ligands in the enantioselective alkylation of benzaldehyde using diethylzinc was studied.
Approach to a better under-standing and modelling of β-pyrrolidinoalcohol ligands for enantioselective alkylation β-pyrrolidinoalcohol derivatives of malic acid, citramalic acid and pantolactone were synthesized and tested in the enantioselective alkylation of benzaldehyde with diethylzinc. The insight into the mechanism of chiral induction contributes to the design of new ligands. Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 250, Issues 1–2, 2 May 2006, Pages 104–113
Journal: Journal of Molecular Catalysis A: Chemical - Volume 250, Issues 1–2, 2 May 2006, Pages 104–113
نویسندگان
António M. d’A. Rocha Gonsalves, M. Elisa S. Serra, Dina Murtinho,