کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
688252 | 1460107 | 2013 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Characteristics of integrated micro packed bed reactor-heat exchanger configurations in the direct synthesis of dimethyl ether Characteristics of integrated micro packed bed reactor-heat exchanger configurations in the direct synthesis of dimethyl ether](/preview/png/688252.png)
• Three different integrated micro packed bed reactor-heat exchange configurations.
• Direct DME synthesis over CuO–ZnO–Al2O3/γ-Al2O3 mixtures at 50 bar and 220–320 °C.
• Isobaric and isothermal reaction environment free from transport limitations.
• Narrow RTD predicted from dispersion analysis.
• Potential for process intensification of the direct DME synthesis identified.
The performance of three integrated micro packed bed reactor-heat exchangers (IMPBRHEs) for direct DME synthesis over physical mixtures of CuO–ZnO–Al2O3 and γ-Al2O3 catalysts was experimentally investigated. Systematic variations in reactor and slit dimensions and configuration were analyzed in terms of thermal behaviour, mass transfer, pressure drop and residence time distribution (RTD). The pressure drop was always small (<0.12 bar) relative to the total pressure (50 bar), and linear dependence with GHSV confirms the predicted laminar flow for Re = 0.1–2. A narrow RTD was estimated by the dispersion analysis. Careful temperature measurements confirmed that the reaction temperature is mainly controlled by the oil heat exchange to give a practically uniform temperature profile for set inlet oil temperatures of 220–320 °C. The micro packed beds were found free of the internal as well as external mass transfer limitations, as showed by no significant change in the CO conversion and DME yield for different catalyst particle sizes, no effect of varying the linear gas velocity, and no effect of manipulating reactant diffusion coefficient. Packed bed microstructured reactors hence provide an isobaric and isothermal environment free from transport limitations for the direct DME synthesis, in the kinetic regime as well as at equilibrium conversion.
Journal: Chemical Engineering and Processing: Process Intensification - Volume 70, August 2013, Pages 77–85