کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
68954 | 48526 | 2006 | 5 صفحه PDF | دانلود رایگان |

Chemical fixation of carbon dioxide with epoxides to form cyclic carbonates proceeds very effectively under mild conditions by using immobilized ionic liquid catalyst in conjunction with zinc chloride without any organic solvents. The reaction temperature, carbon dioxide pressure, effects of different metallic complexes and the amount of immobilized ionic liquid were investigated. The optimum reaction conditions were 110 °C and 1.5 MPa, and the catalyst system was recycled and reused.
Chemical fixation of carbon dioxide with epoxides to form cyclic carbonates proceeds very effectively under mild conditions by using immobilized ionic liquid catalyst in conjunction with zinc chloride without any organic solvents. Reaction temperature, carbon dioxide pressure, effects of different metallic complexes and the amount of immobilized ionic liquid were investigated. The optimum reaction conditions were 110 °C and 1.5 MPa, and the catalyst system was recycled and reused. Figure optionsDownload as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 253, Issues 1–2, 1 July 2006, Pages 265–269