کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
69074 48529 2006 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Highly efficient Barbier allylation from allyl alcohol using iridium(I)/tin(II): Unusual and indirect roles of allyl alcohol and tin
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Highly efficient Barbier allylation from allyl alcohol using iridium(I)/tin(II): Unusual and indirect roles of allyl alcohol and tin
چکیده انگلیسی

A reagent combination of SnCl2 and catalytic [Ir(COD)Cl]2 (1 mol%) in THF–H2O promotes the reaction of allyl alcohol and aldehyde leading to homoallyl alcohols in good to excellent yields. Control studies suggest the plausible participation of π-allyl-iridium intermediate(s) from which direct allyl transfer takes place to aldehyde.

Facile one-carbon homologation of allyl alcohol to homoallyl alcohol using IrI–SnCl2 as reagent is described, which might involve the intermediacy of a π-allyl-iridium intermediate. Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 246, Issues 1–2, 1 March 2006, Pages 231–236
نویسندگان
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