کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
69102 | 48530 | 2006 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Dendritic BIPHEP: Synthesis and application in asymmetric hydrogenation of β-ketoesters Dendritic BIPHEP: Synthesis and application in asymmetric hydrogenation of β-ketoesters](/preview/png/69102.png)
A series of new chiral dendritic BIPHEP ligands have been prepared and their applications in the Ru-catalyzed asymmetric hydrogenation of β-ketoesters were investigated. Ruthenium catalysts containing these dendrimer ligands were effective in the hydrogenation of β-ketoesters. It was found that the size of the dendritic wedges influenced the enantioselectivity significantly.
New kind of chiral dendritic BIPHEP ligands have been prepared and their applications in the Ru-catalyzed asymmetric hydrogenation of β-ketoesters were investigated. Ruthenium catalysts containing these dendrimer ligands were effective in the hydrogenation of β-ketoesters. It was found that the size of the dendritic wedges influenced the enantioselectivity significantly.Figure optionsDownload as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 244, Issues 1–2, 1 February 2006, Pages 118–123