کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
691405 | 1460433 | 2014 | 13 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Potential of waste pumice and surface modified pumice for hexavalent chromium removal: Characterization, equilibrium, thermodynamic and kinetic study
ترجمه فارسی عنوان
پتانسیل پومیس زباله و پمیز اصلاح شده سطحی برای حذف کروم شش ظرفیتی: مشخصات، تعادل، مطالعه ترمودینامیکی و جنبشی
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کلمات کلیدی
جذب، کروم شش ظرفیتی، آزمایش های دسته ای، تعادل، سینتیک، پومیس،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تکنولوژی و شیمی فرآیندی
چکیده انگلیسی
The sorption potential of natural (NP) and surface modified pumice using MgCl2 (MGMP) as an abundant and low cost geo-material for the removal of Cr(VI) ion was investigated. The influence of contact time, solution pH, initial metal concentration, amount of absorbents and solution temperature was studied. Natural and modified adsorbents were characterized by means of XRD, XRF, SEM and FTIR technologies. Maximum sorption was observed at pH 1 and 100Â mg/L metal concentration. Equilibrium data were accurately fitted onto Langmuir, Freundlich and Temkin isotherms, showing the heterogeneous nature of the adsorbents; maximum sorption capacity according to the Langmuir isotherm were 87.72Â mg/g and 105.43Â mg/g for NP and MGMP, respectively, showing a high sorption potential if compared to adsorbents used for Cr(VI) removal. Intra-particle model demonstrated that film diffusion was the rate-limiting step instead of intra-particle diffusion, as confirmed from the analysis of pseudo-second order rate constants, showing an absence of limitation due to pore diffusion. Relevance of pumice was confirmed since high regeneration yields were obtained, 94.3% in acidic conditions (1Â M HCl) for spent non-modified pumice and 91.3% in alkaline conditions (4Â M NaOH) for spent modified pumice.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of the Taiwan Institute of Chemical Engineers - Volume 45, Issue 2, March 2014, Pages 635-647
Journal: Journal of the Taiwan Institute of Chemical Engineers - Volume 45, Issue 2, March 2014, Pages 635-647
نویسندگان
Mohammad Noori Sepehr, Abdeltif Amrane, Kamal Aldin Karimaian, Mansur Zarrabi, Hamid Reza Ghaffari,