کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
69190 | 48532 | 2006 | 4 صفحه PDF | دانلود رایگان |
Metallophthalocyanines bearing substituents are found to be efficient catalysts for nitrene transfer reactions. Under optimized reaction conditions, aziridination of alkenes and amidation of CH bonds with PhI = NTs by using 3-trifluromethylphenyoxy-substituted phthalocyanine-iron complex led to the highest yields of 90% and 85% for 4-methylstyrene and 4-ethyltoluene, respectively.
Metallophthalocyanines bearing substituents are found to be efficient catalysts for nitrene transfer reaction. Under optimized reaction conditions, aziridination of alkenes and amidation of CH bonds with PhI = NTs by using 3-trifluromethylphenyoxy-substituted iron-phthalocyanine complex led to the highest yields of 90% and 85% for 4-methylstyrene and 4-methylethylbenzene, respectively. Figure optionsDownload as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 248, Issues 1–2, 3 April 2006, Pages 148–151