کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
691962 | 1460460 | 2009 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Isothermal vapor-liquid equilibria for binary mixtures of hexane, heptane, octane, nonane and cyclohexane at 333.15Â K, 343.15Â K and 353.15Â K
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تکنولوژی و شیمی فرآیندی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Isothermal vapor-liquid equilibria at 333.15 K, 343.15 K and 353.15 K for four binary mixtures of hexane + heptane, heptane + octane, cyclohexane + octane and cyclohexane + nonane have been obtained at pressures ranged from 0 to 101.3 kPa. The NRTL, UNIQUAC and Wilson activity coefficient models have been employed to correlate experimental pressures and liquid mole fractions. The non-ideal behavior of the vapor phase has been considered by using the Soave-Redlich-Kwong equation of state in calculating the vapor mole fraction. Liquid and vapor densities were also measured by using two vibrating tube densitometers. Phase behaviors of the P-x-y diagrams indicate that three mixtures of hexane + heptane, heptane + octane, cyclohexane + octane were close to the ideal solution. However, the cyclohexane + nonane mixture presents a large positive deviation from the ideal solution. Only the cyclohexane + octane mixture is negative in the excess Gibbs energy indicates that it is an exothermic system.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of the Taiwan Institute of Chemical Engineers - Volume 40, Issue 5, September 2009, Pages 573-579
Journal: Journal of the Taiwan Institute of Chemical Engineers - Volume 40, Issue 5, September 2009, Pages 573-579
نویسندگان
Kun-Jung Lee, Wei-Kuan Chen, Jing-Wei Ko, Liang-Sun Lee, Chieh-Ming J. Chang,