Synthesis and characterization of organic fluorine and nano-SiO2 modified polyacrylate emulsifier-free latex

- Nano-SiO2/fluorinated polyacrylate was synthesized by soap-free emulsion polymerization.
- Hybrid film had a rough surface and an excellent hydrophobicity.
- Nano-SiO2 can improve the solvent-resistant and mechanical properties of hybrid film.