کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
692326 1460515 2015 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Thermomechanical and corrosion inhibition properties of graphene/epoxy ester–siloxane–urea hybrid polymer nanocomposites
ترجمه فارسی عنوان
خواص مهار حرارتی و خوردگی گرافن / اپوکسی استرا سیلوکسانا اوره نانوکامپوزیت های پلیمری هیبرید
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تکنولوژی و شیمی فرآیندی
چکیده انگلیسی


• Coatings containing low amount of graphene showed remarkable corrosion resistance.
• Coated aluminum alloy did not corrode after 20 weeks of immersion in seawater.
• Filled coatings show remarkably high rubbery plateau storage modulus.
• A correlation between the rubbery plateau modulus and corrosion resistance is made.

The effect of graphene on the corrosion inhibition properties of a hybrid epoxy–ester–siloxane–urea polymer was investigated. The weight fraction of graphene was varied from 1 to 2 wt%. Direct current polarization (DCP) and electrochemical impedance spectroscopic (EIS) techniques were used to measure the polarization and coating resistance of the coated aluminum alloy substrate. The grapheme/hybrid polymer composite coatings showed much higher corrosion inhibition property when compared to the neat hybrid polymer coating. An increase in glass transition temperature and rubbery region modulus was also observed for composites containing 1–2 wt.% of graphene. A direct correlation between the rubbery plateau modulus of free standing composite thin films and corrosion resistance of the composite coatings was made, indicating that the corrosion protection mechanism is due to restriction of the polymer chain motion by graphene which causes a decrease in coating permeability.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Progress in Organic Coatings - Volume 88, November 2015, Pages 237–244
نویسندگان
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