کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
69242 48534 2006 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Supported polyperoxometallates: Highly selective catalyst for oxidation of alcohols to aldehydes
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Supported polyperoxometallates: Highly selective catalyst for oxidation of alcohols to aldehydes
چکیده انگلیسی

A new highly selective heterogeneous catalyst is developed from phosphomolybdic acid for the oxidation of alcohols by supporting polyoxomolybdate anions on vanadium–aluminum mixed oxide. The Keggin anion was found to be stable on the surface of vanadium–aluminum mixed oxide unlike alumina. It was further observed to undergo degradation with peroxide, to form surface bound polyperoxomolybdate species. In order to examine its usefulness, the catalyst was screened for the oxidation of variety of alcohols, using hydrogen peroxide under solid–liquid–liquid phase transfer conditions to yield corresponding aldehydes with almost 100% selectivity. In all the substrates examined, no traceable amount of over oxidised product was detected.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 243, Issue 2, 16 January 2006, Pages 244–252
نویسندگان
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