کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
693917 889909 2006 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Chromate leaching from inhibited primers: Part II: Modelling of leaching
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تکنولوژی و شیمی فرآیندی
پیش نمایش صفحه اول مقاله
Chromate leaching from inhibited primers: Part II: Modelling of leaching
چکیده انگلیسی

Leaching profiles for two chromate-inhibited epoxy polyamide primers have been analysed and non-Fickian diffusion kinetics have been observed. The time dependence was found to be t0.25 instead of the standard Fickian t0.5. The t0.25 time dependence was consistent for different pH values (1, 3, 5 and 7) even though the overall release rates increased with decreasing pH. Abrading the primer surface increased the overall leaching rate but did not change the t0.25 dependence. The unusual release kinetics cannot be explained by a decreasing effective diffusion coefficient (via changes in porosity and tortuosity or a fractal structure) or pH-dependent chemical reactions. The leaching rates have been modelled using a simple power law, a polynomial, and the shrinking core model. The polynomial model produced the best fit to leaching data and provides some insight into the source of the non-Fickian leaching behaviour.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Progress in Organic Coatings - Volume 56, Issue 1, 1 May 2006, Pages 33–38
نویسندگان
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