کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6967876 | 1453003 | 2018 | 17 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Abatement of SF6 in the presence of NH3 by dielectric barrier discharge plasma
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this paper, the degradation rate, energy yield and the degradation by-products of SF6 was studied when different concentrations of NH3 were added. When NH3 concentration increased from 0 to 2%, the degradation rate efficiency(DRE) of SF6 increased from 60% to 97.23% under the flow rate of 50ml/min and 94W input power. The energy yield(EY) reached 4.16g/kWh. In addition, we found that increasing the flow rate to 250ml/min, the DRE decreased to 58.71%, but the EY increased to 12.55g/kWh. The main gas by-products are SOF2, SO2F2, SO2, OF2, HF and NF3. When the concentration of initial NH3 increased, the SO2 concentration increased while the concentrations of SOF2, SO2F2, SOF4 decreased. In addition, we found that a pale yellow film formed on the surface of the reactor wall. XPS analysis showed that the solid products were mainly S, NH3HF and NH4HF2. The emission spectra show that NH3 addition can effectively promote the formation of active particles and increase plasma density.The addition of NH3 can convert some of the sulfur and fluorine into solid products and reduce the production of toxic gases.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 360, 15 October 2018, Pages 341-348
Journal: Journal of Hazardous Materials - Volume 360, 15 October 2018, Pages 341-348
نویسندگان
Xiaoxing Zhang, Zhaolun Cui, Yalong Li, Hanyan Xiao, Yi Li, Ju Tang, Song Xiao,