کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6972400 | 1453099 | 2013 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Adsorption of lanthanum (III) from aqueous solution using 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester-grafted magnetic silica nanocomposites
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In view of increasing attention of magnetic materials in the field of separation science and technology, we provide an effective route for fabrication of a new magnetic material with high adsorption capacity and selectivity toward metal ions, excellent acid resistance property and long service life. Silica was firstly coated on the magnetic particles, and then silane-coupling agent (3-chloropropyltryethosysilane) was used for grating 2-ethylhexyl phosphonic acid mono-2-ethylhexyl (P507), an organophosphorous acid extractant, on the surface of magnetic silica nanocomposite. The amount of P507 anchored on the particle was estimated to be 0.43Â mmol/g. The P507-grafted magnetic silica nanocomposite was stable over pH range of 0-14. The maximum adsorption capacity of La (III) was 55.9Â mg/g at the optimized pH 5.5. The adsorption of La (III) on our nanocomposites was found to follow the second order kinetics equation and fit Langmuir isotherm model well. The PO functional groups took an important role in the coordination and adsorption mechanism, which was confirmed by FTIR and XPS techniques. After 10 adsorption/desorption cycles, no obvious decrease in adsorption capacity or obvious loss in saturation magnetization were observed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 260, 15 September 2013, Pages 409-419
Journal: Journal of Hazardous Materials - Volume 260, 15 September 2013, Pages 409-419
نویسندگان
Dongbei Wu, Yanhong Sun, Qigang Wang,