کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7006004 1455137 2018 17 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Mathematical modelling of the evolution of the particle size distribution during ultrasound-induced breakage of aspirin crystals
ترجمه فارسی عنوان
مدل سازی ریاضی تکامل توزیع اندازه ذرات در هنگام شکستگی ناشی از سونوگرافی از کریستال های آسپیرین
کلمات کلیدی
سونوگرافی، مدل سازی توازن جمعیت، بلورسازی، تکنولوژی ذرات، برآورد سینتیک،
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
چکیده انگلیسی
While the effects of ultrasound on crystals have been heavily investigated experimentally, population balance models that describe the effects of all physical parameters such as solution viscosity and applied power on the crystal size distribution have been lacking. This article presents one of the first population balance models for describing the crystal breakage that results from ultrasound. Aspirin crystals dispersed in various solvents, dodecane and silicon oils of known viscosity, were subjected to ultrasound to study this sonofragmentation that occurs due to cavitation when bubbles violently collapse, creating extreme conditions in the immediate vicinity of the bubbles. Population balance models are developed with three models for binary breakage events and cavitation rate proportional to the applied power and exponentially related to solvent viscosity. The resulting population balance models provide reasonable agreement with the experimental data over the ranges of applied power and solvent viscosity investigated, with nearly overlapping crystal size distributions for applied power between 10 and 40 W. The statistical analysis supports the breakage model in which cavitation bubbles cause the aspirin crystals to break into two equal-sized particles.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Research and Design - Volume 132, April 2018, Pages 170-177
نویسندگان
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