Plasma-etched electrospun nanofiber membrane as adsorbent for dye removal

The removal of hazardous dyes from wastewater is essential for environmental remediation. A simple, green and effective air plasma etching treatment was introduced to fabricate PLLA nanofibrous adsorbents. The cationic methylene blue (MB) dye could be rapidly adsorbed on the surface of plasma-etched PLLA nanofiber membrane through electrostatic interaction. It was attributed to the increased surface area and the generated binding sites after the plasma treatment. The adsorption behavior was influenced by both the plasma etching time and the initial MB concentration. It was found that the adsorption kinetics fits well with the pseudo-second order model, and the isotherm data fits well with the Langmuir model, revealing that monolayer MB was chemically adsorbed on the adsorbent. Moreover, the plasma-etched PLLA nanofiber membrane has also exhibited good reusability. It is believed that the plasma treatment may facilitate the design and fabrication of a new class of nanofibrous adsorbents.