کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7019614 | 1455935 | 2018 | 32 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Mid-block quaternized polystyrene-b-polybutadiene-b-polystyrene triblock copolymers as anion exchange membranes
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
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چکیده انگلیسی
A novel mid-block, side-chain-type quaternized triblock copolymer was prepared from commercial polystyrene-b-polybutadiene-b-polystyrene (SBS) triblock copolymers by Markovnikov addition reaction with HBr, azidation, and Cu(I)-catalyzed click reaction for high-performance anion exchange membranes (AEM). After the optimization of reaction conditions, the bromination, azidation and subsequently Cu(I)-catalyzed click reactions have been confirmed to be quantitative according to the NMR results. The anion-conductive, mid-block triblock copolymer (SBS-c-QA) membrane was obtained from casting its DMF solution. As a control experiment, the mid-block quaternized SBS (SBS-QA) membrane was also synthesized by direct quaternization of brominated SBS with trimethylamine. The SBS-c-QA membrane with pendent quaternary ammounium groups showed much lower water uptake than that of SBS-QA membrane. However, comparable bicarbonate conductivities of 5.6â¯mS/cm at 20â¯Â°C and 20.5 mS/cm at 80â¯Â°C were obtained for SBS-c-QA membrane in spite of its low ion exchange capacity (IEC) (1.10â¯meq./g) and low water uptake (18â¯wt%). Thus, the SBS-c-QA membrane displayed high IEC-normalized conductivity which can be attributed to the side-chain architecture of the triblock copolymer. The alkaline stability testing indicated that SBS-c-QA membrane showed a higher alkaline stability than SBS-QA membrane. A high retention of bicarbonate conductivity (70%) was observed after degradation testing in 1â¯M NaOH at 80â¯Â°C for 216â¯h. These results suggested that incorporating the side-chain-type QA cations into the mid-block of the triblock copolymer was an effective method to fabricate AEMs with both high ionic conductivity and excellent alkaline stability.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 564, 15 October 2018, Pages 428-435
Journal: Journal of Membrane Science - Volume 564, 15 October 2018, Pages 428-435
نویسندگان
Lei Liu, Danfeng Li, Yi Xing, Nanwen Li,