کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
702634 1460807 2012 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Carbon nanostructures: A morphological classification for charge density optimization
موضوعات مرتبط
مهندسی و علوم پایه سایر رشته های مهندسی مهندسی برق و الکترونیک
پیش نمایش صفحه اول مقاله
Carbon nanostructures: A morphological classification for charge density optimization
چکیده انگلیسی

Nanostructured carbons offer great promise in numerous electrode applications due to their high surface area and area specific capacitance. With the growing importance of energy applications in particular, a need has emerged to characterize the various forms of activated and nanostructured carbons in the context of their electrochemical charge-storage capacity. However, the use of gravimetric or area specific capacitance can be uninformative or even misleading due to the critical role of exposed linear edge density on charge-transfer processes; edges exhibit approximately 20 × greater specific capacitance than basal planes. Thus, a more robust normalization is needed for materials that possess this extreme anisotropy. By classifying nanostructures based on linear edge density, a deeper understanding of materials performance can be obtained and a more informed comparison of nanostructures is enabled. This report provides a classification of carbon nanostructures based on the dimensional organization of their edge structures. Morphological benchmarks of the classification are provided, including a novel graphenated CNT hybrid which increases the linear edge density of nanostructured carbons by an order of magnitude. Geometric consideration of the dimensional nature of the edge organization enables quantification of the edge density per unit nominal area.


► Linear edge density (ρL) was approximated for each carbon nano-structure.
► Electron Density of Graphene Edges (EDGE) Triangle maps different nano-structures.
► The EDGE Triangle is organized based on dimensional structure of sp2 bonded edges.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Diamond and Related Materials - Volume 23, March 2012, Pages 130–134
نویسندگان
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