کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
703125 891127 2007 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Characterization of phases synthesized close to the boundary of C60 collapse at high temperature high pressure conditions
موضوعات مرتبط
مهندسی و علوم پایه سایر رشته های مهندسی مهندسی برق و الکترونیک
پیش نمایش صفحه اول مقاله
Characterization of phases synthesized close to the boundary of C60 collapse at high temperature high pressure conditions
چکیده انگلیسی

Two sets of samples were synthesized at high pressure high temperature conditions in the P–T region where C60 molecules collapse into a nearly amorphous graphite-like hard carbon phase. For the first set, heating temperature was varied at fixed pressure and preparation time. For the second set, synthesis time was varied at fixed pressure and fixed temperature. Detailed structural characterization of samples was performed using Raman spectroscopy and powder XRD. Mechanical properties of the samples have been studied by nanoindentation method. It has been found that duration of heat treatment under high pressure is an important parameter which influences the temperature of fullerene cage collapse. Both tetragonal and rhombohedral polymeric phases transform into hard carbon phase over a rather narrow temperature interval, but the tetragonal phase shows somewhat increased stability against C60 collapse. Viscoelastic mechanical behavior during nanoindentation was observed for fullerene polymers but not for graphite-like hard carbon phase. Possible mechanism for nucleation of the hard carbon phase in polymeric C60 networks is discussed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Diamond and Related Materials - Volume 16, Issue 8, August 2007, Pages 1550–1556
نویسندگان
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