کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7078988 | 1459987 | 2014 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Devolatilisation kinetics and pyrolytic analyses of Tectona grandis (teak)
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تکنولوژی و شیمی فرآیندی
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چکیده انگلیسی
Devolatilisation kinetics and pyrolytic analyses were carried out on Tectona grandis (teak) using iso-conversional methods (Flynn-Wall-Ozawa and Starink) and analytical Py-GC/MS technique respectively. Proximate and elemental analyses were also performed and they showed that the ash and C contents and the HHV were 0.7%, 49.6% and 19.8 MJ/kg respectively. Biomass sample was subjected to multiple heating rates (5-35 K/min) in thermogravimetric experiments and kinetic parameters were evaluated from the non-isothermal TGA curves. The activation energy (E) varied between 222 and 300 kJ/mol as a function of degree of conversion. Similarly, the pre-exponential frequency factor (A) varied between 9.6 Ã 1017 and 9.55 Ã 1024 minâ1. Analytical Py-GC/MS showed the presence of CO2, acetic acid, furan + 2-butanone, levoglucosan, trans-coniferyl alcohol and lignin derivatives. The proportion of phenolic compounds identified was more than one-third with isoeugenol, acetoguaiacone, and 4-vinylguaiacol showing dominance.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Bioresource Technology - Volume 156, March 2014, Pages 57-62
Journal: Bioresource Technology - Volume 156, March 2014, Pages 57-62
نویسندگان
A.O. Balogun, O.A. Lasode, A.G. McDonald,