Chemoenzymatic synthesis of α-l-rhamnosides using recombinant α-l-rhamnosidase from Aspergillus terreus

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- α-l-Rhamnosidase was heterologously produced in P. pastoris.
- Chemoenzymatic rhamnosylation of alcohols was optimized using full factorial setup.
- Phenolic acceptors can be glycosylated with α-l-rhamnosidase using free rhamnose.