کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7082430 1460001 2013 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Highly efficient Michael-type addition of acetaldehyde to β-nitrostyrenes by whole resting cells of Escherichia coli expressing 4-oxalocrotonate tautomerase
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تکنولوژی و شیمی فرآیندی
پیش نمایش صفحه اول مقاله
Highly efficient Michael-type addition of acetaldehyde to β-nitrostyrenes by whole resting cells of Escherichia coli expressing 4-oxalocrotonate tautomerase
چکیده انگلیسی

- Biocatalyst based on whole cells and 4-oxalocrotonate tautomerase was developed.
- (S)-4-nitro-3-phenyl-butanal was obtained in high optical purity (>99% ee) and yield.
- Biotransformation products were amenable to further chemical derivatizations.
- Michael addition of acetaldehyde to halo substituted β-nitrostyrenes was achieved.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Bioresource Technology - Volume 142, August 2013, Pages 462-468
نویسندگان
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