کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7232400 1644974 2015 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Fluorescence sensing of chromium (VI) and ascorbic acid using graphitic carbon nitride nanosheets as a fluorescent “switch”
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Fluorescence sensing of chromium (VI) and ascorbic acid using graphitic carbon nitride nanosheets as a fluorescent “switch”
چکیده انگلیسی
Using graphitic carbon nitride (g-C3N4) nanosheets, an effective and facile fluorescence sensing approach for the label-free and selective determination of chromium (VI) (Cr(VI)) was developed. The fluorescence of the solution of g-C3N4 nanosheets was quenched effectively by Cr(VI) via the inner filter effect. Under optimal conditions, a wide detection linear range for Cr(VI) was found to be from 0.6 μM to 300 μM with a limit of detection (LOD) of 0.15 μM. In addition, the fluorescence of the solution of g-C3N4 nanosheets-Cr(VI) could be sensitively turned on in the presence of a reductant such as ascorbic acid (AA) via an “on-off-on” fluorescence response through the oxidation-reduction between Cr(VI) and AA. And a wide detection linear range for AA was found to be from 0.5 μM to 200 μM with an LOD of 0.13 μM. Furthermore, the proposed method has the potential application for detection of Cr(VI) in lake waters and AA in biological fluids.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Biosensors and Bioelectronics - Volume 68, 15 June 2015, Pages 210-217
نویسندگان
, , , , , , , , ,