کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7596452 | 1492127 | 2014 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Drying process of sodium alginate films studied by two-dimensional correlation ATR-FTIR spectroscopy
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
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چکیده انگلیسی
Drying process of aqueous sodium alginate solutions at 50 °C was investigated by ATR-FTIR spectroscopy and two-dimensional correlation infrared spectroscopy. Two-dimensional asynchronous spectrum at 1800-1350 cmâ1 wavenumber could be resolved into five separate bands, which were assigned to O-H bending vibrations in water (around 1645 cmâ1), antisymmetric and symmetric stretching vibrations of free and hydrogen-bonded COOâ groups of alginate (around 1595, 1412, 1572 and 1390 cmâ1, respectively). As the drying process progressed, absorbance bands at around 1127 and 1035 cmâ1 significantly shifted to lower wavenumbers (1120 and 1027 cmâ1, respectively). Suggesting that oxygen atoms at the 2th and 3th position in the pyranose ring might have hydrogen bonded with water or alginate chains. Further analysis using 2D asynchronous correlation spectroscopy between 1800-1500 and 1200-960 cmâ1 wavenumber regions revealed the sequence of spectral changes during the drying process.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Food Chemistry - Volume 164, 1 December 2014, Pages 179-184
Journal: Food Chemistry - Volume 164, 1 December 2014, Pages 179-184
نویسندگان
Qian Xiao, Xiaohong Gu, Suo Tan,