Dihydrolipoyl dioleoylglycerol antioxidant capacity in phospholipid vesicles

► Chemo-enzymatically produced dihydrolipoyl dioleoylglycerol. ► Dihydrolipoyl dioleoylglycerol is an effective antioxidant in liposomes. ► Splayed configuration has lipoyl group oriented towards bilayer interfacial region.