کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7694606 1496486 2015 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Artificial hydrogenase: biomimetic approaches controlling active molecular catalysts
ترجمه فارسی عنوان
هیدروژنه مصنوعی: روشهای بیوموژن برای کنترل کاتالیزورهای مولکولی فعال
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
چکیده انگلیسی
Hydrogenase catalyses reversible transformation of H2 to H+ using an active site which includes an iron or nickel atom. Synthetic model complexes and molecular catalysts inspired by nature have unveiled the structural and functional basis of the active site with remarkable accuracy and this has led to the discovery of active synthetic catalysts. To further improve the activity of such molecular catalysts, both the first and outer coordination spheres should be well-organized and harmonized for an efficient shuttling of H+, electrons, and H2. This article reviews recent advances in the design and catalytic properties of artificial enzymes that mimic the hydrogenase active site and the outer coordination sphere in combination with a peptide or protein scaffold.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Current Opinion in Chemical Biology - Volume 25, April 2015, Pages 133-140
نویسندگان
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