کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7705378 | 1497295 | 2018 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Enhanced thermal diffusivity and dehydrogenation of 2LiNH2MgH2 by doping with super activated carbon
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Doping with the additives in metal-N-H system has been regarded as one of the most effective approaches to improve its hydrogen storage properties. Herein, we prepared super activated carbon (SuperC) through the activation of commercial activated carbon by KOH and evaluated its effect on dehydrogenation properties of 2LiNH2MgH2. Our studies show that doping with SuperC could effectively lower its dehydrogenation temperatures. For instance, 2LiNH2MgH2-10 wt% SuperC can release 4.86 wt% of hydrogen upon heating up to 300 °C with the onset and peak dehydrogenation temperatures of 71 °C and 168 °C, respectively. Moreover, the release of byproduct NH3 was successfully suppressed. Measurement of thermal diffusivity suggests that the enhanced dehydrogenation properties may be ascribed to the improved heat transfer for solid-solid reaction resulting from doping with SuperC.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 43, Issue 30, 26 July 2018, Pages 13975-13980
Journal: International Journal of Hydrogen Energy - Volume 43, Issue 30, 26 July 2018, Pages 13975-13980
نویسندگان
Shujun Qiu, Wei Gao, Xingyu Ma, Hailiang Chu, Yongjin Zou, Cuili Xiang, Huanzhi Zhang, Fen Xu, Lixian Sun,