Improving rate capability and decelerating voltage decay of Li-rich layered oxide cathodes by chromium doping

In order to improve the rate capability and mitigate the voltage decay of lithium rich layered oxides, chromium doped cathode materials Li1.2[Mn0.54Ni0.13Co0.13]1−xCrxO2 (x = 0,0.003,0.005,0.007) is synthesized via co-precipitation method followed by calcination. As a result, Cr-doped samples present shortened voltage platform at 4.5 V, indicating that the escape of lattice oxygen is suppressed by Cr doping. Among all samples, Li1.2[Mn0.54Ni0.13Co0.13]1−xCrxO2 (x = 0.005) sample shows the greatest rate capability (119.3 mAh g−1 at 10 C) and the minimum voltage drop (0.6167 V) after 200 cycles at 1.0 C. The reasons for the improved electrochemical performance are the enhanced structural stability, the stronger CrO bond than MnO band and the decreased metal-oxygen covalency induced by Cr doping.