کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7707620 | 1497318 | 2018 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and optimization of new polymeric ionic liquid poly(diallydimethylammonium) bis(trifluoromethane sulfonyl)imde based gel electrolyte films
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis and optimization of new polymeric ionic liquid poly(diallydimethylammonium) bis(trifluoromethane sulfonyl)imde based gel electrolyte films Synthesis and optimization of new polymeric ionic liquid poly(diallydimethylammonium) bis(trifluoromethane sulfonyl)imde based gel electrolyte films](/preview/png/7707620.png)
چکیده انگلیسی
Polymeric ionic liquid-based gel electrolyte films are a new generation of electrolyte materials for flexible energy storage device applications. In this work, Li-ion conducting gel electrolyte films are prepared with the polymeric ionic liquid poly(diallydimethylammonium) bis(trifluoromethane sulfonyl)imide (poly(DADMATFSI)) as the host polymer and the lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt as the dopant. The crystalline nature, thermal stability, ionic conductivity and electrochemical stability window of the polymeric electrolyte films are analyzed by various characterization techniques. It is found that the polymeric electrolyte films exhibit high flexibility and excellent thermal stability. Their room-temperature electrical conductivity increases with increasing LiTFSI concentration and reaches a high value of 1.00 Ã 10â3 S cmâ1 at 20 wt% LiTFSI. The ionic transference numbers of the polymeric electrolyte films are in the range of 0.98-0.99, indicating that they are perfect ion conductors. Finally, the electrochemical stability window of the 20 wt% LiTFSI-doped polymeric electrolyte film is determined as approximately 6 V, which is a promising value for flexible energy storage device applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 43, Issue 7, 15 February 2018, Pages 3741-3749
Journal: International Journal of Hydrogen Energy - Volume 43, Issue 7, 15 February 2018, Pages 3741-3749
نویسندگان
Xingcheng Hu, Ravi Muchakayala, Shenhua Song, Jingwei Wang, Jianjun Chen, Manlin Tan,