کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7707628 1497318 2018 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Applying isotropic strain on Mo to predict H solution behaviors for nuclear energy application: Temperature dependence
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Applying isotropic strain on Mo to predict H solution behaviors for nuclear energy application: Temperature dependence
چکیده انگلیسی
The solution and bubble formation of hydrogen (H) in molybdenum (Mo) are fundamental and crucial factors for Mo as a plasma facing component under a fusion environment, but data are presently scarce. High energy neutron irradiated Mo inevitably leads to a local strain, which may change the solubility of H in Mo. Here we performed first-principles calculations to predict the H solution properties under isotropic strain combined with temperature effect in Mo and found that the H solubility can be improved/inhibited by tensile/compressive strain at the temperature range 300-1800 K. The calculated H solubility presents good agreement with the experimental results under the strain-free case. Together our former results of anisotropic strain, both isotropic and anisotropic strains enhance H solution so as to give an underlying physical implication for H bubble formation in Mo: strain enhance H solubility to result in the nucleation of H bubble that further causes the local strain of lattice surrounding the bubble, which by turns improves the H solubility at the non-uniformly strained region that promotes continuously growing up of bubble via a chain-reaction effect in Mo. This result can also interpret the H bubble formation even if no radiation damage is produced in Mo.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 43, Issue 7, 15 February 2018, Pages 3750-3760
نویسندگان
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