کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7708825 | 1497326 | 2017 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
CoRh nanoparticles supported on ZIF-67 as highly efficient catalysts for hydrolytic dehydrogenation of ammonia boranes for chemical hydrogen storage
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: CoRh nanoparticles supported on ZIF-67 as highly efficient catalysts for hydrolytic dehydrogenation of ammonia boranes for chemical hydrogen storage CoRh nanoparticles supported on ZIF-67 as highly efficient catalysts for hydrolytic dehydrogenation of ammonia boranes for chemical hydrogen storage](/preview/png/7708825.png)
چکیده انگلیسی
Extremely diffused bimetallic CoRh nanoparticles supported on ZIF-67 have been triumphantly compounded by using a simple wet-chemical approach and then they were characterized by ICP-AES, power XRD, N2 adsorption-desorption, HTEM, EDX, SEM and XPS. In the midst of the texted catalysts, the catalytic activity of the Rh25Co75@ZIF-67 catalysts is the highest, with turnover frequency (TOF) value of 100.21mol H2.minâ1(mol catalyst)â1, and 100% H2 selectivity at 298â¯K. Additionally, the durability of this catalyst is very excellent for five cycles.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 51, 21 December 2017, Pages 30037-30043
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 51, 21 December 2017, Pages 30037-30043
نویسندگان
Qu Xiaopeng, Yu Zhiqiang, Li Zeping, Gui Xiangyu, Jiang Rui, Xu Zhimou, Chen Cunhua, Peng Jing,