Hetero-/homogeneous combustion of premixed hydrogen-oxygen mixture in a micro-reactor with catalyst segmentation

Numerical simulations with detailed homogeneous (gas phase) and heterogeneous (catalytic) chemistries of premixed hydrogen-oxygen mixture were performed inside a rectangular micro-combustor. The effects of catalytic walls on the homogeneous combustion were investigated via varying catalyst segment layouts and sizes. The interactions between heterogeneous and homogeneous reactions were discussed. It was shown that the heterogeneous reactions become weak when the catalyst disposition is shifted toward the outlet along the streamwise. The homogeneous combustion also becomes obviously weakened downstream behind the catalyst segmentation, except the exit. Moreover, with increasing catalyst segment size, the hydrogen conversion ratio increases and the mean outlet temperature reduces. The competition of the fresh fuel between the heterogeneous and homogeneous reactions result in the inhibition of heterogeneous reactions on homogeneous combustion. In summary, the heterogeneous reactions can obviously improve the combustion efficiency in a micro catalytic combustor. As expected, the effects of catalytic walls were more pronounced for the micro combustor systems.