کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7713410 | 1497427 | 2015 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Hydrogen sorption and desorption behaviors of metal-carbon composites prepared by alcohol CVD method
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In order to provide with novel composites with high specific surface area for hydrogen storage, FeNiCr-carbon composites were prepared by an alcohol chemical vapor deposition (ACCVD) method with methanol as a carbon source, wherein the abbreviation FeNiCr denoted powdery mixture of hydrogenated Fe, Ni and Cr. After the ACCVD synthesis, the composites were optionally ground to expose inner sorption sites. The peak temperature of hydrogen desorption from as-prepared FeNiCr-carbon composite hydrogenated at 653Â K under 1.1Â MPa of hydrogen was 723Â K, as recorded by temperature programmed desorption (TPD). The peak temperature of hydrogen desorption from ground FeNiCr-carbon composite hydrogenated under the same conditions was as low as 423Â K. HD molecules were detected by TPD, after the ground FeNiCr-carbon composite was similarly hydrogenated at 653Â K under mixed H2 plus D2 gas. Such was also the case, after the ground composite was hydrogenated at room temperature. It was evidenced that atomic hydrogen took part in hydrogen sorption by the ground composite. The maximum hydrogen concentrations of the FeNiCr-carbon composites were 0.59 mass% and 1.16 mass%, before and after grinding, respectively, at 77Â K under 0.77Â MPa of hydrogen.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 40, Issue 46, 14 December 2015, Pages 16323-16329
Journal: International Journal of Hydrogen Energy - Volume 40, Issue 46, 14 December 2015, Pages 16323-16329
نویسندگان
Takehiro Kaneko, Yasuhiro Watanuki, Takeshi Toyama, Yoshiyuki Kojima, Nobuyuki Nishimiya,